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排序方式: 共有1379条查询结果,搜索用时 15 毫秒
31.
In photo-induced graft copolymerization of methyl methacrylate onto cellulose, the effect of metallic ions as sensitizer was investigated. Some metallic ions were effective in their adsorbed states and accelerated the formation of grafts in the order Fe2+ > Ag+ > Fe3+. However, Cu2+ acted negatively, and little effect was observed for Co2+, Ni2+, Mn2+, Zn2+, and Cr3+. In the systems in which aqueous metallic salt solutions were added, the formation of grafts was generally depressed, but Fe3+ was an exception. The effect of metallic ions on the scission reaction of cellulose main chains did not necessarily agree with the effect on the formation of grafts. This is attributed to the varied interaction between cellulose and the different active species produced by irradiation, depending on the type of metallic ions used. 相似文献
32.
The effect of sodium thiosulfate on the graft copolymerization of methyl methacrylate to cellulose in the hydrogen peroxide initiator system was investigated. The addition of sodium thiosulfate in general was effective for decreasing the per cent grafting and the average molecular weight of grafts and increasing the formation of homopolymer, and the effects became pronounced with increasing hydrogen peroxide concentration. Moreover, the addition of sodium thiosulfate slightly suppressed the formation of grafts at a hydrogen peroxide concentration of 3 mmole/l., but greatly promoted it at 20 mmole/l. Traces of metallic ions present in cellulose could not be eliminated sufficiently by treatment with 3N hydrochloric acid. Such ions were found to interact with hydrogen peroxide and thus participate directly in the initiation and termination of the polymerization reaction. EDTA, the chelating agent, was highly effective for suppressing such participation of metallic ions. In the hydrogen peroxide initiator system applied to the EDTA-treated samples, sodium thiosulfate caused an effective initiation of graft formation. 相似文献
33.
Warm deep drawing of wrought magnesium alloy sheets produced by semi-solid roll strip-casting process 总被引:1,自引:0,他引:1
H. Watari N. Koga K. Davey T. Haga M.T. Alonso Ragado 《International Journal of Machine Tools and Manufacture》2006,46(11):1233-1237
This paper is concerned with the development of a continuous strip-casting technology to facilitate the manufacture of magnesium sheet alloys economically whilst maintaining high quality. Established in the paper is warm formability of cast magnesium alloy sheets after being hot rolled by semi-solid roll strip-casting process. It has been found that magnesium sheet with 2.0–4.0 mm thickness could be produced at a speed of 25 m/min. Hot rolling and annealing temperatures during hot rolling were also changed to examine which condition would be appropriate for producing wrought magnesium alloys with good formability. Microstructures of the crystals of the manufactured wrought magnesium alloys were observed. It has been found that a limiting drawing ratio of 2.7 was possible in a warm deep-drawing test of the cast magnesium alloy sheets after being hot rolled. 相似文献
34.
Naoji Shiroma Ryo Miyauchi Akira Nagafusa Youhei Haga Fumitoshi Matsuno 《Advanced Robotics》2015,29(3):149-163
In robot teleoperation, a robot works as a physical agent at a remote site for a robot operator. There are mainly two tasks in robot teleoperation using camera images: environment recognition using visual information and robot control according to the recognition. In this paper, we propose a gaze direction based vehicle teleoperation method with an omnidirectional image stabilization and an automatic body rotation control. In the proposed method, we manage above two tasks in the same manner that are usually treated separately. This method is an intuitive vehicle teleoperation method where an operator do not need to have concern about vehicle body orientations and can absorb differences of vehicle driving mechanisms. That is, this method frees an operator from being bothered from controlling a vehicle and the operator can concentrate on where he/she intends to go. This method mainly consists of two technologies: an omnidirectional image stabilization technology and automatic body rotation control. The conducted experiments show effectiveness of the proposed method. 相似文献
35.
Ken-ichi Kohichi Hiroyuki Shiro Satoshi Hitoshi Atsushi 《Sensors and actuators. B, Chemical》2008,130(2):707-712
Pt-loaded metal oxides [WO3/ZrO2, MOx/TiO2 (MOx = WO3, MoO3, V2O5), WO3 and TiO2] equipped with interdigital Au electrodes have been tested as a NOx (NO and NO2) gas sensor at 500 °C. The impedance value at 4 Hz was used as a sensing signal. Among the samples tested, Pt-WO3/TiO2 showed the highest sensor response magnitude to NO. The sensor was found to respond consistently and rapidly to change in concentration of NO and NO2 in the oxygen rich and moist gas mixture at 500 °C. The 90% response and 90% recovery times were as short as less than 5–10 s. The impedance at 4 Hz of the present device was found to vary almost linearly with the logarithm of NOx (NO or NO2) concentration from 10 to 570 ppm. Pt-WO3/TiO2 showed responses to NO and NO2 of the same algebraic sign and nearly the same magnitude, while Pt/WO3 and WO3/TiO2 showed higher response to NO than NO2. The impedance at 4 Hz in the presence of NO for Pt-WO3/TiO2 was almost equal at any O2 concentration examined (1–99%), while in the case of Pt/WO3 and WO3/TiO2 the impedance increased with the oxygen concentration. The features of Pt-WO3/TiO2 are favorable as a NOx sensor that can monitor and control the NOx concentration in automotive exhaust. The effect of WO3 loading of Pt-WO3/ZrO2-based sensor is studied to discuss the role of surface W-OH sites on the NOx sensing. 相似文献
36.
Cecilia Laschi Gioel Asuni Eugenio Guglielmelli Giancarlo Teti Roland Johansson Hitoshi Konosu Zbigniew Wasik Maria Chiara Carrozza Paolo Dario 《Autonomous Robots》2008,25(1-2):85-101
This paper presents a sensory-motor coordination scheme for a robot hand-arm-head system that provides the robot with the capability to reach an object while pre-shaping the fingers to the required grasp configuration and while predicting the tactile image that will be perceived after grasping. A model for sensory-motor coordination derived from studies in humans inspired the development of this scheme. A peculiar feature of this model is the prediction of the tactile image. The implementation of the proposed scheme is based on a neuro-fuzzy module that, after a learning phase, starting from visual data, calculates the position and orientation of the hand for reaching, selects the best-suited hand configuration, and predicts the tactile feedback. The implementation of the scheme on a humanoid robot allowed experimental validation of its effectiveness in robotics and provided perspectives on applications of sensory predictions in robot motor control. 相似文献
37.
We describe a direct x-ray imaging system that uses an amplified metal-oxide-semiconductor imager to detect soft x rays directly for real-time imaging. From the absolute sensitivity of this system as measured through the use of a monochromatic synchrotron radiation beam and a GaAsP Schottky-type photodiode, the minimum sensitivity at a wavelength of 13 nm was estimated to be greater than 10(8)photons mm(-2). This is sufficient to detect soft x rays directly for real-time imaging. Onion cell observations at wavelengths of 4.3 and 4.6 nm indicate that x-ray absorption by the carbon in the cells was detected. This is a promising imaging system for the soft x-ray region in which conventional CCD's are difficult to use. 相似文献
38.
Engineering Transition Metal Layers for Long Lasting Anionic Redox in Layered Sodium Manganese Oxide
Natalia Voronina Jun Ho Yu Hee Jae Kim Najma Yaqoob Olivier Guillon Hyungsub Kim Min-Gi Jung Hun-Gi Jung Koji Yazawa Hitoshi Yashiro Payam Kaghazchi Seung-Taek Myung 《Advanced functional materials》2023,33(5):2210423
Oxygen-redox-based-layered cathode materials are of great importance in realizing high-energy-density sodium-ion batteries (SIBs) that can satisfy the demands of next-generation energy storage technologies. However, Mn-based-layered materials (P2-type Na-poor Nay[AxMn1−x]O2, where A = alkali ions) still suffer from poor reversibility during oxygen-redox reactions and low conductivity. In this work, the dual Li and Co replacement is investigated in P2-type-layered NaxMnO2. Experimentally and theoretically, it is demonstrated that the efficacy of the dual Li and Co replacement in Na0.6[Li0.15Co0.15Mn0.7]O2 is that it improves the structural and cycling stability despite the reversible Li migration from the transition metal layer during de-/sodiation. Operando X-ray diffraction and ex situ neutron diffraction analysis prove that the material maintains a P2-type structure during the entire range of Na+ extraction and insertion with a small volume change of ≈4.3%. In Na0.6[Li0.15Co0.15Mn0.7]O2, the reversible electrochemical activity of Co3+/Co4+, Mn3+/Mn4+, and O2-/(O2)n- redox is identified as a reliable mechanism for the remarkable stable electrochemical performance. From a broader perspective, this study highlights a possible design roadmap for developing cathode materials with optimized cationic and anionic activities and excellent structural stabilities for SIBs. 相似文献
39.
Tatsuhiko Matsumoto Satoru Kubota Yuta Kubota Kenta Imabayashi Kazuyuki Kishimoto Seiichi Goshi Shigeki Imai Youichi Igarashi Shuichi Haga Takehiro Nakatsue 《Journal of the Society for Information Display》2011,19(11):813-820
Abstract— To understand actual viewing conditions at home is important for TV design. And the preferred luminance level of LCD TVs under actual viewing conditions is also important in order to obtain both good picture quality and low power consumption. The actual viewing conditions of households and the preferred luminance levels was investigated. In a field test of 83 households, the display luminance, screen illuminance, and viewing locations were measured on site. In laboratory experiments, young and elderly subjects adjusted the luminance of an LCD‐TV screen to their preferred levels under different screen illuminance levels, angular screen sizes, and average luminance levels (ALL) of the images. As a result, two equations, which represent the preferred luminance level of LCD‐TV screens corresponding to different viewing conditions for young and elderly subjects were obtained. When the ALL of the images was 25% and the screen illuminance and angular screen size were set at 100 lx and 20°, respectively, the preferred luminance was 1 60 cd/m2 for the young subjects and 248 cd/m2 for the elderly subjects. By using the setting of the preferred luminance of an LCD TV under actual viewing conditions, it is possible to conserve energy consumption. 相似文献
40.
Fusaomi Nagata Takanori Mizobuchi Shintaro Tani Tetsuo Hase Zenku Haga Keigo Watanabe Maki K. Habib 《Artificial Life and Robotics》2010,15(1):106-110
In this article, a new desktop orthogonal-type robot, which has the capacity of stick-slip motion control based on cutter
location data, is presented for lapping small metallic molds with a curved surface. The robot consists of three single-axis
devices with a high position resolution of 1 μm. A thin wooden stick tool with a ball-end shape is attached to the tip of
the z-axis. In order to improve the lapping performance, a novel stick-slip motion control method is developed in the control system.
The small stick-slip motion is orthogonally generated in the direction of the tool’s movement. The effectiveness of stick-slip
motion control is examined through an actual lapping test of an LED lens cavity. 相似文献